粉煤灰制备混凝剂及其砸黄河水的处理效果

以粉煤灰和铁泥为原料、加入一定量NaCl作助溶剂室温下制备粉煤灰混凝剂，考察酸灰比与酸浓度对Fe3＋、Al“溶出率及混凝剂对黄河水处理效果的影响。结果表明，Fe3＋、A13＋的最佳溶出条件为酸灰比3mL／g、HCl浓度4mol／L，此时Fe“溶出率为28．1％，浓度为11．81g／L；A13＋溶出率为5．2％，浓度为1．86g／L。粉煤灰混凝剂对黄河水的处理效果在投加量2．38mL／L、沉降时间30min、pH6．2～7．5时最佳，对浊度、ss和COD。。平均去除率分别为89．7％、83．6％和62．3％，优于传统市售混凝剂PAC和Fc，Fe3＋、AI3＋同时存在有利于各自优势的发挥从而提高混凝效果。     

中国下一个绿色十年

<正>一年多以前,胡锦涛主席在纽约向世界郑重承诺,中国将在2020年之前将二氧化碳排放强度降低40%～45%。此外,第十七届五中全会将"包容性增长"作为未来经济发展主旋律,促进经济平衡发展,使更多的人能够享受到中国经济发展带来的好处。"包容性增长"的提出对于中国西部地区的发展至关重要。在西部大开发的过程中,能否找到一种既可以提高当地人民生活水平,又能够有力保护自然资源的办法对于中国而     

The potential risk assessment for different arsenic species in the aquatic environment

The different toxicity characteristics of arsenic species result in discrepant ecological risk.The predicted no-effect concentrations(PNECs) 43.65, 250.18, and 2.00 × 103μg/L were calculated for As(III), As(V), and dimethylarsinic acid in aqueous phase, respectively. With these PNECs, the ecological risk from arsenic species in Pearl River Delta in China and Kwabrafo stream in Ghana was evaluated. It was found that the risk from As(III) and As(V)in the samples from Pearl River Delta was low, while much high in Kwabrafo stream. This study implies that ecological risk of arsenic should be evaluated basing on its species.     

A hybrid procedure for MSW generation forecasting at multiple time scales in Xiamen City,China

Accurate forecasting of municipal solid waste (MSW) generation is crucial and fundamental for the planning, operation and optimization of any MSW management system. Comprehensive information on waste generation for month-scale, medium-term and long-term time scales is especially needed, considering the necessity of MSW management upgrade facing many developing countries. Several existing models are available but of little use in forecasting MSW generation at multiple time scales. The goal of this study is to propose a hybrid model that combines the seasonal autoregressive integrated moving average (SARIMA) model and grey system theory to forecast MSW generation at multiple time scales without needing to consider other variables such as demographics and socioeconomic factors. To demonstrate its applicability, a case study of Xiamen City, China was performed. Results show that the model is robust enough to fit and forecast seasonal and annual dynamics of MSW generation at month-scale, medium- and long-term time scales with the desired accuracy. In the month-scale, MSW generation in Xiamen City will peak at 132.2 thousand tonnes in July 2015 – 1.5 times the volume in July 2010. In the medium term, annual MSW generation will increase to 1518.1 thousand tonnes by 2015 at an average growth rate of 10%. In the long term, a large volume of MSW will be output annually and will increase to 2486.3 thousand tonnes by 2020 – 2.5 times the value for 2010. The hybrid model proposed in this paper can enable decision makers to develop integrated policies and measures for waste management over the long term.     

人体动力特性振动台试验研究

随着社会发展和经济水平的提高,人们对于生产、生活的环境质量要求也不断提升,因而环境振动已越来越多的引起了社会的关注,为了研究环境振动对人体的影响,需要了解人体动力特性和在振动环境下的响应。对20名受试者以站、坐、躺姿进行了水平两向输入白噪声的振动台试验,测得人体头、肩、腹、上肢、下肢五个部位的振动响应,通过对人体各部分振动频率与身高、体重、年龄的关系分析,给出了人体频率分布规律。     

Speciated Hydrocarbon Emissions from the Combustion of Single Component Fuels. I. Effect of Fuel Structure

Speciated hydrocarbon emissions data have been collected for six single-component fuels run in a laboratory pulse flame combustor (PFC). The six fuels include n-heptane, isooctane (2, 2, 4-trimethylpentane), cyclohexane, 1-hexene, toluene, and methyl-t-butyl ether (MTBE: an oxygenated fuel extender). Combustion of non-aromatic fuels in the PFC (at a fuel/air equivalence ratio of Φ = 1.02) produced low levels of unburned fuel and high yields of methane and olefins (> 75 percent combined) irrespective of the molecular structure of the fuel. In contrast, hydrocarbon emissions from toluene combustion in the PFC were comprised predominantly of unburned fuel (72 percent). With the PFC, low levels of 1, 3-butadiene (0.3-1.8 percent) were observed from all the fuels except MTBE, for which no measurable level (<0.2 percent) was detected; low levels of benzene were observed from isooctane, heptane, and 1-hexene, but significant levels (9 percent) from cyclohexane and toluene. No measurable amount of benzene (< 0.2 percent) was observed in the MTBE exhaust.

For isooctane and toluene the speciated hydrocarbon emissions from a spark-ignited (SI) single-cylinder engine were also determined. HC emissions from the SI engine contained the same species as observed from the PFC, although the relative composition was different. For the non-aromatic fuel isooctane, unburned fuel represented a larger fraction (50 percent) of the HC emissions when run in the engine. HC emissions from toluene combustion in the engine were similar to those from the PFC.     

灾后承接非政府组织援助系统工程的综合集成模式——以汶川8.0级地震为例

分析了承接非政府组织(NGO)援助复杂巨系统的框架结构、时空结构、运行结构及整体特性;提出了地震灾后承接援助系统工程的综合集成模式;分别就承接援建集成工程的运作模式和具体实施框架进行了讨论;就援建系统工程、迎建系统工程、应急组织系统工程和保障系统工程等具体实施工程做了细致的阐述。     

Trends in vehicular emissions in China's mega cities from 1995 to 2005

Multiyear inventories of vehicular emissions in Beijing, Shanghai and Guangzhou from 1995 through 2005 have been developed in this paper to study the vehicle emissions trends in China's mega cities during the past decade. The results show that the vehicular emissions of CO, HC, NO_x and PM₁₀ have begun to slow their growth rates and perhaps even to decline in recent years due to the implementation of measures to control vehicular emissions in these cities. However, vehicular CO₂ emissions have substantially increased and still continue to grow due to little fuel economy improvement. Passenger cars and large vehicles (including heavy duty trucks and buses) are the major sources of vehicular CO₂ and CO emissions while large vehicles were responsible for nearly 70% and 80% of the vehicular NO_x and PM₁₀ emissions in these mega cities. Motorcycles are also important contributors to vehicular emissions in Guangzhou and Shanghai.     

Homology modeling of anti-parathion antibody and its interaction with organophosphorous pesticides and analogues

The mechanism of specific recognition in pesticide immunochemistry was investigated by computer-based strategy, and a rapid method for the identification of antibody specificity was developed. Based on the previously produced anti-parathion monoclonal antibody (mAb), the DNA sequence was analyzed by polymerase chain reaction (PCR). From the translated amino acid sequences, a three-dimensional structure of the antibody was constructed by homology modeling method, and then it was coordinated by 1 ns molecular dynamics under the explicit solvent condition. The stereochemical property and folding quality were further assessed by Procheck and Profile-3D. The self-compatibility score for the antibody model was 98.7, which was greater than the low score 46.2 and close to the top score 102.6. In addition, parathion and several structural analogues were docked to the constructed antibody structure. The docking results showed that the interaction energy (-40.54 kcal/mol) of antibody-parathion complex was the lowest among all the tested pesticides, which accounted for the high specificity of the antibody to parathion and perfectly matched with the experimental data. Moreover, three residues, Phe165, Asp107 and Thr100 were recognized as the most important residues for antibody reacting with parathion. The interaction energy negatively correlated with the antibody specificity.     

Influence of flooding and metal immobilising soil amendments on availability of metals for willows and earthworms in calcareous dredged sediment-derived soils

Soil amendments previously shown to be effective in reducing metal bioavailability and/or mobility in calcareous metal-polluted soils were tested on a calcareous dredged sediment-derived soil with 26 mg Cd/kg dry soil, 2200 mg Cr/kg dry soil, 220 mg Pb/kg dry soil, and 3000 mg Zn/kg dry soil. The amendments were 5% modified aluminosilicate (AS), 10% w/w lignin, 1% w/w diammonium phosphate (DAP, (NH₄)₂HPO₄), 1% w/w MnO, and 5% w/w CaSO₄. In an additional treatment, the contaminated soil was submerged. Endpoints were metal uptake in Salix cinerea and Lumbricus terrestris, and effect on oxidation-reduction potential (ORP) in submerged soils. Results illustrated that the selected soil amendments were not effective in reducing ecological risk to vegetation or soil inhabiting invertebrates, as metal uptake in willows and earthworms did not significantly decrease following their application. Flooding the polluted soil resulted in metal uptake in S. cinerea comparable with concentrations for an uncontaminated soil.